Structure and intramolecular lability of N-(thio)phosphoryl(thio)amides: V. Dynamic properties of crown-containing N,N′-bis(thio)phosphoryl(thio)carbonylamides by 1H, 13C, and 31P NMR spectroscopy

dc.contributor.author	Karataeva F.
dc.contributor.author	Klochkov V.
dc.date.accessioned	2018-09-17T21:23:27Z
dc.date.available	2018-09-17T21:23:27Z
dc.date.issued	1999
dc.identifier.issn	1070-3632
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/134929
dc.description.abstract	The structure and intramolecular transformations of the N,N′-bis[diisopropoxy(thio)phosphoryl(thio)carbonyl]-1,10-diaza-18-crown-6 ethers in CCl4, CDCl3, CD2Cl2, (CD3)2CO, and CD3CN solutions were studied by 1H, 13C, and 31P NMR spectroscopy. It was found that the compounds under study are highly labile in solution and exist as a variety of tautomers and conformers. The C=O- and P=S-containing derivative was proposed to undergo intermolecular tautomerization.
dc.relation.ispartofseries	Russian Journal of General Chemistry
dc.title	Structure and intramolecular lability of N-(thio)phosphoryl(thio)amides: V. Dynamic properties of crown-containing N,N′-bis(thio)phosphoryl(thio)carbonylamides by 1H, 13C, and 31P NMR spectroscopy
dc.type	Article
dc.relation.ispartofseries-issue	7
dc.relation.ispartofseries-volume	69
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	1131
dc.source.id	SCOPUS10703632-1999-69-7-SID0033235382

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Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.