Reactions of Phosphorylsulfenyl Chlorides with 2H-1,2,3-Diazaphospholes

dc.contributor.author	Khusainova N.
dc.contributor.author	Zyablikova T.
dc.contributor.author	Reshetkova G.
dc.contributor.author	Lamm E.
dc.contributor.author	Cherkasov R.
dc.date.accessioned	2018-09-17T21:22:55Z
dc.date.available	2018-09-17T21:22:55Z
dc.date.issued	1998
dc.identifier.issn	1070-3632
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/134917
dc.description.abstract	Formation of a quasiphosphonium salt in reaction of phosphorylsulfenyl chlorides with 1,2,3-diazaphospholes was established by dynamic 31P NMR spectroscopy. The salt is formed by addition of 2 mol of phosphorylsulfenyl chloride to the σ2λ3P=C endocyclic fragment by the 1,1- and 1,2-addition schemes. Decomposition of the salt yields mainly O,O-dialkyl phosphothiochloridate and, to a lesser extent, dialkyl phosphochloridate.
dc.relation.ispartofseries	Russian Journal of General Chemistry
dc.title	Reactions of Phosphorylsulfenyl Chlorides with 2H-1,2,3-Diazaphospholes
dc.type	Article
dc.relation.ispartofseries-issue	9
dc.relation.ispartofseries-volume	68
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	1411
dc.source.id	SCOPUS10703632-1998-68-9-SID0032243250

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