dc.contributor.author |
Galkina I. |
|
dc.contributor.author |
Sobanov A. |
|
dc.contributor.author |
Galkin V. |
|
dc.contributor.author |
Cherkasov R. |
|
dc.date.accessioned |
2018-09-17T21:22:53Z |
|
dc.date.available |
2018-09-17T21:22:53Z |
|
dc.date.issued |
1998 |
|
dc.identifier.issn |
1070-3632 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/134916 |
|
dc.description.abstract |
Salicylaldehyde, unlike benzaldehyde, sets the Kabachnik-Fields reaction on the way of initial imine formation. This is explained by the thermodynamic instability of hydroxyphosphonates derived from salicyalaldehyde, which blocks the second possible Kabachnik-Fields reaction route involving intermediate hydroxyphosphonate formation. The kinetics and mechanism of addition of dialkyl hydrogen phosphites at the C=N bond of the intermediate N-substituted imines (the final stage of the "imine" Kabachnik-Fields reaction) are well consistent with the earlier proposed unified reaction mechanism. |
|
dc.relation.ispartofseries |
Russian Journal of General Chemistry |
|
dc.title |
Kinetics and Mechanism of the Kabachnik-Fields Reaction: IV. Salicyaldehyde in the Kabachnik-Fields Reaction |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
9 |
|
dc.relation.ispartofseries-volume |
68 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
1398 |
|
dc.source.id |
SCOPUS10703632-1998-68-9-SID0032236119 |
|