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dc.contributor.author | Galkina I. | |
dc.contributor.author | Sobanov A. | |
dc.contributor.author | Galkin V. | |
dc.contributor.author | Cherkasov R. | |
dc.date.accessioned | 2018-09-17T21:22:53Z | |
dc.date.available | 2018-09-17T21:22:53Z | |
dc.date.issued | 1998 | |
dc.identifier.issn | 1070-3632 | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/134916 | |
dc.description.abstract | Salicylaldehyde, unlike benzaldehyde, sets the Kabachnik-Fields reaction on the way of initial imine formation. This is explained by the thermodynamic instability of hydroxyphosphonates derived from salicyalaldehyde, which blocks the second possible Kabachnik-Fields reaction route involving intermediate hydroxyphosphonate formation. The kinetics and mechanism of addition of dialkyl hydrogen phosphites at the C=N bond of the intermediate N-substituted imines (the final stage of the "imine" Kabachnik-Fields reaction) are well consistent with the earlier proposed unified reaction mechanism. | |
dc.relation.ispartofseries | Russian Journal of General Chemistry | |
dc.title | Kinetics and Mechanism of the Kabachnik-Fields Reaction: IV. Salicyaldehyde in the Kabachnik-Fields Reaction | |
dc.type | Article | |
dc.relation.ispartofseries-issue | 9 | |
dc.relation.ispartofseries-volume | 68 | |
dc.collection | Публикации сотрудников КФУ | |
dc.relation.startpage | 1398 | |
dc.source.id | SCOPUS10703632-1998-68-9-SID0032236119 |