Electrochemical Oxidation of Azacrown Transition Metal Complexes on a Graphite Electrode

dc.contributor.author	Shaidarova L.
dc.contributor.author	Fedorova I.
dc.contributor.author	Ulakhovich N.
dc.contributor.author	Budnikov G.
dc.date.accessioned	2018-09-17T21:22:23Z
dc.date.available	2018-09-17T21:22:23Z
dc.date.issued	1998
dc.identifier.issn	1070-3632
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/134904
dc.description.abstract	Azacrown compounds and their 3d-transition metal complexes undergo oxidation on a graphite electrode in aqueous and organic solutions. The macrocyclic ligands are oxidized to radical cations which are involved in further electrode reactions. The one-electron oxidation of diazabenzo-18-crown-6 and triazabenzo-18-crown-6 is reversible. Diaza-18-crown-6, as well as cyclam and its derivatives are oxidized irreversibly and at more positive potentials. The central atom in the species resulting from the oxidation of the Co(II), Ni(II), and Cu(II) complexes has the oxidation state 3+. The voltammetric characteristics of the oxidation of the macrocyclic complexes are solvent-dependent.
dc.relation.ispartofseries	Russian Journal of General Chemistry
dc.title	Electrochemical Oxidation of Azacrown Transition Metal Complexes on a Graphite Electrode
dc.type	Article
dc.relation.ispartofseries-issue	1
dc.relation.ispartofseries-volume	68
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	10
dc.source.id	SCOPUS10703632-1998-68-1-SID0032380631

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