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dc.contributor.author | Kiselev V. | |
dc.contributor.author | Kashaeva E. | |
dc.contributor.author | Luzanova N. | |
dc.contributor.author | Konovalov A. | |
dc.date.accessioned | 2018-09-17T21:21:54Z | |
dc.date.available | 2018-09-17T21:21:54Z | |
dc.date.issued | 1997 | |
dc.identifier.issn | 1070-3632 | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/134892 | |
dc.description.abstract | The integral enthalpies of dissolution of lithium perchlorate in diethyl ether, acetone, acetonitrile, and dimethyl sulfoxide were determined by calorimetry at 298.2 K: -6.2, -9.1, -15.9, and -18.0 kcal/mol, respectively. The concentration dependence of the integral enthalpy of dissolution of lithium perchlorate in diethyl ether was established in the range from 3x10-3 to 5.6 M. The exothermic effect of dissolution in ether decreases from -6 to -5 kcal/mol at low salt concentrations (3x10-3-3x10-2 M), remains constant in the range of salt concentrations from 5x10-2-1.3 M, and then smoothly decreases to -3.2 kcal/mol at a salt concentration of 5.6 M. | |
dc.relation.ispartofseries | Russian Journal of General Chemistry | |
dc.title | Enthalpies of Dissolution of Lithium Perchlorate in Diethyl Ether, Acetone, Acetonitrile, and Dimethyl Sulfoxide and Its Acceleration Effect on Cycloaddition Reactions | |
dc.type | Article | |
dc.relation.ispartofseries-issue | 9 | |
dc.relation.ispartofseries-volume | 67 | |
dc.collection | Публикации сотрудников КФУ | |
dc.relation.startpage | 1361 | |
dc.source.id | SCOPUS10703632-1997-67-9-SID0031352861 |