Complexation and Spectroscopic and Electrochemical Characteristics of Platinum(II) and Palladium(II) Chelates with N-(Thio)phosphorylated Thioamides

dc.contributor.author	Mashkina S.
dc.contributor.author	Pestova N.
dc.contributor.author	Ulakhovich N.
dc.contributor.author	Zabirov N.
dc.date.accessioned	2018-09-17T21:20:54Z
dc.date.available	2018-09-17T21:20:54Z
dc.date.issued	1996
dc.identifier.issn	1070-3632
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/134869
dc.description.abstract	In dioxane and acetonitile solutions N-(thio)phosphorylated thiobenzamide and thioacetamide form stable chelates with Pd(II) and Pt(II) ions. The composition (1:2) and the stability constants of these chelates were determined by spectrophotometry. The electrochemical behavior of these complexes was studied in DMF solutions. The electroreduction mechanism depends strongly both on substituents in the thiocarbonyl fragment of the ligand and on the central ion. The formation of Pd(I) complexes in the first step of electroreduction of the thiobenzamide complexes was determined by ESR spectroscopy.
dc.relation.ispartofseries	Russian Journal of General Chemistry
dc.title	Complexation and Spectroscopic and Electrochemical Characteristics of Platinum(II) and Palladium(II) Chelates with N-(Thio)phosphorylated Thioamides
dc.type	Article
dc.relation.ispartofseries-issue	4
dc.relation.ispartofseries-volume	66
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	515
dc.source.id	SCOPUS10703632-1996-66-4-SID0030335273

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