dc.contributor.author |
Romakhin A. |
|
dc.contributor.author |
Kosachev I. |
|
dc.contributor.author |
Nikitin E. |
|
dc.date.accessioned |
2018-09-17T21:20:04Z |
|
dc.date.available |
2018-09-17T21:20:04Z |
|
dc.date.issued |
1996 |
|
dc.identifier.issn |
1070-3632 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/134855 |
|
dc.description.abstract |
Electrochemical oxidation of trialkyl phosphites and dialkyl trimethylsilyl phosphites in the presence of olefins yields mixtures of isomeric dialkyl alkenyl(cycloalkenyl)phosphonates with predominating [alken(cycloalken)-2-yl]phosphonates. A scheme of the process was proposed, which involves attack of the alkene double bond by anodically generated radical cations of phosphites, followed by a second electron transfer, deprotonation, and elimination of cationic species: alkyl cation in the case of trialkyl phosphites and trimethylsilyl cation in the case trimethylsilyl phosphites. |
|
dc.relation.ispartofseries |
Russian Journal of General Chemistry |
|
dc.title |
Reaction of Olefins with Anodically Generated Radical Cations of Trialkyl Phosphites and Dialkyl Trimethylsilyl Phosphites |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
12 |
|
dc.relation.ispartofseries-volume |
66 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
1901 |
|
dc.source.id |
SCOPUS10703632-1996-66-12-SID0030310748 |
|