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dc.contributor.author | Romakhin A. | |
dc.contributor.author | Kosachev I. | |
dc.contributor.author | Nikitin E. | |
dc.date.accessioned | 2018-09-17T21:20:04Z | |
dc.date.available | 2018-09-17T21:20:04Z | |
dc.date.issued | 1996 | |
dc.identifier.issn | 1070-3632 | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/134855 | |
dc.description.abstract | Electrochemical oxidation of trialkyl phosphites and dialkyl trimethylsilyl phosphites in the presence of olefins yields mixtures of isomeric dialkyl alkenyl(cycloalkenyl)phosphonates with predominating [alken(cycloalken)-2-yl]phosphonates. A scheme of the process was proposed, which involves attack of the alkene double bond by anodically generated radical cations of phosphites, followed by a second electron transfer, deprotonation, and elimination of cationic species: alkyl cation in the case of trialkyl phosphites and trimethylsilyl cation in the case trimethylsilyl phosphites. | |
dc.relation.ispartofseries | Russian Journal of General Chemistry | |
dc.title | Reaction of Olefins with Anodically Generated Radical Cations of Trialkyl Phosphites and Dialkyl Trimethylsilyl Phosphites | |
dc.type | Article | |
dc.relation.ispartofseries-issue | 12 | |
dc.relation.ispartofseries-volume | 66 | |
dc.collection | Публикации сотрудников КФУ | |
dc.relation.startpage | 1901 | |
dc.source.id | SCOPUS10703632-1996-66-12-SID0030310748 |