Protolytic and complexing properties of 2-alkylaminomethylphenols with respect to copper(II) in aqueous ethanol

dc.contributor.author	Sal'nikov Y.
dc.contributor.author	Boos G.
dc.contributor.author	Ryzhkina I.
dc.contributor.author	Kudryavtseva L.
dc.date.accessioned	2018-09-17T21:19:48Z
dc.date.available	2018-09-17T21:19:48Z
dc.date.issued	2000
dc.identifier.issn	1070-3284
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/134849
dc.description.abstract	The acid-base and complexing properties of 2-butyl- (HL1), octyl- (HL2), dibutyl- (HL3), and dipentylaminophenol (HL4) in aqueous ethanol were characterized by spectrophotometry, pH measurements, and mathematic modeling of equilibria in solutions [T = 25 ± 0.05°C, μ = 0.1 (KNO3)]. The factors increasing and reducing the basicity of the amino group and the acidity of the phenol group were shown to compete in the ligands studied. Mono- and dialkylaminomethylphenols containing the same donor atoms form the mononuclear [CuL]+ and [CuL2] complexes and the dinuclear [Cu2(HL1)4]4+ and [Cu2(HL)3L]3+ complexes with the copper(II) cations.
dc.relation.ispartofseries	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
dc.title	Protolytic and complexing properties of 2-alkylaminomethylphenols with respect to copper(II) in aqueous ethanol
dc.type	Article
dc.relation.ispartofseries-issue	2
dc.relation.ispartofseries-volume	26
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	136
dc.source.id	SCOPUS10703284-2000-26-2-SID0033818817

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