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dc.contributor.author | Tatarintseva T. | |
dc.contributor.author | Mikhailov O. | |
dc.date.accessioned | 2018-09-17T21:19:34Z | |
dc.date.available | 2018-09-17T21:19:34Z | |
dc.date.issued | 1997 | |
dc.identifier.issn | 1070-3284 | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/134843 | |
dc.description.abstract | The complexation in the Cu(II)-ligand systems in the thin gelatin layers of immobilized matrices of copper(II) hexacyanoferrate(II), contacting water-alkaline (pH 12.0 ± 0.1) solutions of 1-(4-hydroxy)- and 1-(2-hydroxy)phenyl-3-benzoyl thiocarbamide, is studied. It is established that, under these conditions, the initial act consists in the decomposition of Cu2[Fe(CN)6] to Cu(OH)2. The latter reacts with organic compounds to form chelates. Two {[Cu(HL)(OH)H2O] and [Cu(HL)2]} water-insoluble complexes are found to form in the Cu(II)-1-(4-hydroxy)phenyl-3-benzoyl thiocarbamide system, and three {[Cu(HL)(OH)H2O], [Cu(HL)2], and [Cu2L2]} water-insoluble complexes form in the Cu(II)-1-(2-hydroxy)phenyl-3-benzoyl thiocarbamide system. © 1997 MAEe cyrillic signK Hayκa/Interperiodica Publishing. | |
dc.relation.ispartofseries | Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya | |
dc.title | Complexation of copper(II) with monosubstituted 3-benzoyl thiocarbamide in gelatin-immobilized copper(II) hexacyanoferrate(II) matrices | |
dc.type | Article | |
dc.relation.ispartofseries-issue | 4 | |
dc.relation.ispartofseries-volume | 23 | |
dc.collection | Публикации сотрудников КФУ | |
dc.relation.startpage | 274 | |
dc.source.id | SCOPUS10703284-1997-23-4-SID0141976649 |