Diels - Alder reaction: Effect of internal and external factors on the reactivity of diene - dienophile systems

dc.contributor.author	Konovalov A.
dc.contributor.author	Kiselev V.
dc.date.accessioned	2018-09-17T21:17:44Z
dc.date.available	2018-09-17T21:17:44Z
dc.date.issued	2003
dc.identifier.issn	1066-5285
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/134799
dc.description.abstract	The key factors influencing the Diels - Alder reaction rate at ambient and elevated pressures were elucidated using data on the reactivity of various diene - dienophile systems in usual and Lewis acid-catalyzed Diels-Alder reactions, the reaction enthalpy, complex formation, dissolution, and solvation, and the donor-acceptor properties of the reactants. It was found that taking account of both the orbital interaction energy and the balance of bond rupture and formation energies allows correct prediction of the reaction rate in the absence or in the presence of Lewis acids.
dc.relation.ispartofseries	Russian Chemical Bulletin
dc.subject	Activation volumes
dc.subject	Catalysis
dc.subject	Diels - Alder reaction
dc.subject	Kinetics
dc.subject	Molecular complexes
dc.subject	Reaction enthalpy
dc.subject	Reaction volumes
dc.title	Diels - Alder reaction: Effect of internal and external factors on the reactivity of diene - dienophile systems
dc.type	Review
dc.relation.ispartofseries-issue	2
dc.relation.ispartofseries-volume	52
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	293
dc.source.id	SCOPUS10665285-2003-52-2-SID0038703822

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Публикации сотрудников КФУ Scopus [24551]
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