The reaction of 2-aminomethylphenols and their copper(II) complexes with esters of phosphorus acids

dc.contributor.author	Ryzhkina I.
dc.contributor.author	Kudryavtseva L.
dc.contributor.author	Enikeev K.
dc.contributor.author	Morozov V.
dc.contributor.author	Boos G.
dc.contributor.author	Sal'nikov Y.
dc.date.accessioned	2018-09-17T21:17:31Z
dc.date.available	2018-09-17T21:17:31Z
dc.date.issued	2000
dc.identifier.issn	1066-5285
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/134793
dc.description.abstract	2-Alkyl- and 2-dialkylaminomethylphenols (AMP) with different Hydrophobic substituents at the nitrogen atom and their copper(II) complexes (CAMP) react with the esters of phosphorus acids in aqueous solutions of ethanol in two stages: phosphorylated AMP (PAMP) are formed at the first stage and then hydrolyzed to the corresponding acids. The reactivity of AMP and PAMP significantly decreases when the hydrophobicity and steric hindrances of substituents at the nitrogen atom increase. An inverse dependence was found for CAMP.
dc.relation.ispartofseries	Russian Chemical Bulletin
dc.subject	2-Aminomethylphenols
dc.subject	Acid-base properties
dc.subject	Complex formation
dc.subject	Copper(II)
dc.subject	Esters of phosphorus acids
dc.subject	Hydrolysis
dc.subject	Reactivity
dc.title	The reaction of 2-aminomethylphenols and their copper(II) complexes with esters of phosphorus acids
dc.type	Article
dc.relation.ispartofseries-issue	8
dc.relation.ispartofseries-volume	49
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	1349
dc.source.id	SCOPUS10665285-2000-49-8-SID0034342653

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