Liquid-crystalline CuII and PdII complexes with nonmesogenic ferrocene-containing β-aminovinyl ketone

dc.contributor.author	Kadkin O.
dc.contributor.author	Galyametdinov Y.
dc.contributor.author	Rakhmatullin A.
dc.contributor.author	Mavrin V.
dc.date.accessioned	2018-09-17T21:17:26Z
dc.date.available	2018-09-17T21:17:26Z
dc.date.issued	1999
dc.identifier.issn	1066-5285
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/134791
dc.description.abstract	New liquid-crystalline heteropolynuclear complexes L2M (M = Cu2+ (2a), Pd2+ (2b)) were synthesized by the reactions of C5H5FeC5H4-C6H4NH-C2H2-(CO)-C6H4OC12H25 (1, LH) with copper(II) and palladium(II) acetates. Compound 2b was found to possess monotropic nematic and smectic phases; 2a exhibits the monotropic nematic phase and a phenomenon of "double melting." The compositions and structures of compounds 1 and 2a,b were established by elemental analysis, 1H and 13C NMR, ESR, and IR spectroscopy.
dc.relation.ispartofseries	Russian Chemical Bulletin
dc.subject	Coordination compounds
dc.subject	Ferrocene
dc.subject	Liquid crystals
dc.subject	Metallomesogens
dc.title	Liquid-crystalline CuII and PdII complexes with nonmesogenic ferrocene-containing β-aminovinyl ketone
dc.type	Article
dc.relation.ispartofseries-issue	2
dc.relation.ispartofseries-volume	48
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	381
dc.source.id	SCOPUS10665285-1999-48-2-SID0033473061

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