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Stripping-voltammetric determination of transition metals using electrodes modified by azacrown compounds

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dc.contributor.author Shaidarova L.
dc.contributor.author Ulakhovich N.
dc.contributor.author Fedorova I.
dc.contributor.author Galyametdinov Y.
dc.date.accessioned 2018-09-17T21:05:07Z
dc.date.available 2018-09-17T21:05:07Z
dc.date.issued 1996
dc.identifier.issn 1061-9348
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/134503
dc.description.abstract Voltammetric properties of macrocyclic complexes of transition metals are studied by using a carbon-paste electrode modified by diaza-18-crown-6, Cyclam, and their derivatives. A selective stripping-voltammetric procedure is proposed for determining Ni(II) and Co(II) with a carbon-paste electrode modified by Cyclam and its derivatives. To improve the sensitivity and selectivity of analysis, it is suggested that metal ions be preconcentrated at the surface of the modified electrode by using a 0.1 M NaCl solution as a supporting electrolyte with the following recording of voltammograms in the range from -0.3 to 0.8 V in a 0.1 M KOH solution. The detection limits for Ni(II) and Co(II) are 4 × 10-8 and 1.2 × 10-7 M, respectively. © 1996 MAEe Cyrillic signK Hayκa/Interperiodica Publishing.
dc.relation.ispartofseries Journal of Analytical Chemistry
dc.title Stripping-voltammetric determination of transition metals using electrodes modified by azacrown compounds
dc.type Article
dc.relation.ispartofseries-issue 7
dc.relation.ispartofseries-volume 51
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 687
dc.source.id SCOPUS10619348-1996-51-7-SID2042500674


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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