Self-assembly of the complexes of bipodal thiophosphorylated thioureas

dc.contributor.author	Zabirov N.
dc.contributor.author	Brusko V.
dc.contributor.author	Verat A.
dc.contributor.author	Krivolapov D.
dc.contributor.author	Litvinov I.
dc.contributor.author	Cherkasov R.
dc.date.accessioned	2018-09-17T21:02:25Z
dc.date.available	2018-09-17T21:02:25Z
dc.date.issued	2002
dc.identifier.issn	1042-6507
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/134435
dc.description.abstract	N-Thiophosphorylated thioureas, of general formula [(i-PrO)2 P(S)NHC(S)]2Z (Z = α,ω-diamino(oxy)alkyl or 1,10-diaza-18-crown-6), in the form of potassium salts, react with a number of soft ions (Cd2+, Zn2+, Co2+, Ni2+, Pd2+) to form novel dimeric complexes. The cadmium (Z = HN(CH2)2NH), palladium (Z = HN(CH2)2O(CH2)2NH), and cobalt (Z = 1,10-diaza-18-crown-6) complexes were analyzed by x-ray crystallography. In the former complex, crown cavities remain free. This fact will allow us to obtain "guest-host" complexes with alkali metal cations.
dc.relation.ispartofseries	Phosphorus, Sulfur and Silicon and Related Elements
dc.subject	Bridging ligands
dc.subject	Chelates
dc.subject	Crown compounds
dc.subject	Macrocycles
dc.subject	N-thiophosphorylthioureas
dc.subject	Self-assembly
dc.title	Self-assembly of the complexes of bipodal thiophosphorylated thioureas
dc.type	Conference Paper
dc.relation.ispartofseries-issue	6-7
dc.relation.ispartofseries-volume	177
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	1869
dc.source.id	SCOPUS10426507-2002-177-67-SID84900281817

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Публикации сотрудников КФУ Scopus [24551]
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