dc.contributor.author |
Polozov A. |
|
dc.contributor.author |
Mustaphin A. |
|
dc.contributor.author |
Khotinen A. |
|
dc.date.accessioned |
2018-09-17T21:01:55Z |
|
dc.date.available |
2018-09-17T21:01:55Z |
|
dc.date.issued |
1992 |
|
dc.identifier.issn |
1042-6507 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/134422 |
|
dc.description.abstract |
Cu(OTf)2 and Cu(acac)2 were found to be the most effective catalysts in the reaction of diazo compounds Ph2CN2 (1a), EtOC(O)CHN2 (lb), MeOC(O)CHN2 (1c), MeC(0)CN2C(O)OMe (1d), Cl-CH2C(O)CHN2 (1e) and CH2N2 (1f) with hydrophosphoryl compounds (MeO)2P(O)H (2a), (t-BuO)2P(O)H (2b), Ph(MeO)P(O)H (2c), (EtO)2P(O)H (2d) and (FORMULA OMITTED) resulting in P-C bond formations. Cu, Pd and Rh acetates and Ni(acac)2 have a much lower efficiency. Chlorines in Cl3CC(O)CH2P(O)(OMe)2 (3k) and Cl2CHC(O)CH2P(0)(OMe)2 (31) are reduced in the copper catalysed Atherton-Todd reaction. © 1992, Taylor & Francis Group, LLC. All rights reserved. |
|
dc.relation.ispartofseries |
Phosphorus, Sulfur, and Silicon and the Related Elements |
|
dc.subject |
Catalyst |
|
dc.subject |
diazo compound |
|
dc.subject |
hydrophosphoryl compound |
|
dc.subject |
insertion |
|
dc.subject |
phosphinate |
|
dc.subject |
phosphonate |
|
dc.title |
Insertion of carbenes into p-h bonds. 5. f synthesis of new phosphonates and phosphinates in reactions catalysed by cu, pd, rh, ni complexes |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
1-4 |
|
dc.relation.ispartofseries-volume |
73 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
153 |
|
dc.source.id |
SCOPUS10426507-1992-73-14-SID84884185079 |
|