dc.contributor.author |
Lisitsyn Y. |
|
dc.contributor.author |
Kargin Y. |
|
dc.date.accessioned |
2018-09-17T21:01:26Z |
|
dc.date.available |
2018-09-17T21:01:26Z |
|
dc.date.issued |
2004 |
|
dc.identifier.issn |
1023-1935 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/134410 |
|
dc.description.abstract |
Electrochemical amination of benzene in sulfuric acid electrolytes is studied and experimental conditions for highly efficient synthesis of primary aromatic amino compounds are determined. In the electrolysis of Ti(IV)-NH 2OH-C 6H 6 in 11 M H 2SO 4 solutions containing acetic acid or acetonitrile as organic solvents, aniline and isomeric phenylenediamines are obtained with the total yields by hydroxylamine of 95.6 and 99.6%, respectively. A monoamino compound is the main product of radical substitution in acidic organo-aqueous media. It is found that the use of acetonitrile in electrochemical process is limited to certain sulfuric acid concentrations and temperatures. |
|
dc.relation.ispartofseries |
Russian Journal of Electrochemistry |
|
dc.subject |
amino radical |
|
dc.subject |
electrophilic amination |
|
dc.subject |
hydroxylamine |
|
dc.subject |
radical amino cation |
|
dc.subject |
radical aromatic substitution |
|
dc.title |
Electrochemical amination: Efficiency of a radical substitution |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
9 |
|
dc.relation.ispartofseries-volume |
40 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
977 |
|
dc.source.id |
SCOPUS10231935-2004-40-9-SID4544244301 |
|