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dc.contributor.author | Lisitsyn Y. | |
dc.contributor.author | Kargin Y. | |
dc.date.accessioned | 2018-09-17T21:01:26Z | |
dc.date.available | 2018-09-17T21:01:26Z | |
dc.date.issued | 2004 | |
dc.identifier.issn | 1023-1935 | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/134410 | |
dc.description.abstract | Electrochemical amination of benzene in sulfuric acid electrolytes is studied and experimental conditions for highly efficient synthesis of primary aromatic amino compounds are determined. In the electrolysis of Ti(IV)-NH 2OH-C 6H 6 in 11 M H 2SO 4 solutions containing acetic acid or acetonitrile as organic solvents, aniline and isomeric phenylenediamines are obtained with the total yields by hydroxylamine of 95.6 and 99.6%, respectively. A monoamino compound is the main product of radical substitution in acidic organo-aqueous media. It is found that the use of acetonitrile in electrochemical process is limited to certain sulfuric acid concentrations and temperatures. | |
dc.relation.ispartofseries | Russian Journal of Electrochemistry | |
dc.subject | amino radical | |
dc.subject | electrophilic amination | |
dc.subject | hydroxylamine | |
dc.subject | radical amino cation | |
dc.subject | radical aromatic substitution | |
dc.title | Electrochemical amination: Efficiency of a radical substitution | |
dc.type | Article | |
dc.relation.ispartofseries-issue | 9 | |
dc.relation.ispartofseries-volume | 40 | |
dc.collection | Публикации сотрудников КФУ | |
dc.relation.startpage | 977 | |
dc.source.id | SCOPUS10231935-2004-40-9-SID4544244301 |