Electrochemical amination of benzene in aqueous solutions of sulfuric acid and an organic solvent

dc.contributor.author	Lisitsyn Y.
dc.contributor.author	Kargin Y.
dc.date.accessioned	2018-09-17T21:01:18Z
dc.date.available	2018-09-17T21:01:18Z
dc.date.issued	2003
dc.identifier.issn	1023-1935
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/134407
dc.description.abstract	Electrolysis of the Ti(IV)-NH2OH-C6H6 system in 11 M H2SO4 reveals that out of four organic solvents - methanol, formic acid, acetonitrile, and acetic acid - only the last two meet conditions imposed on solvents to be used in indirect cathodic amination of aromatic compounds. They improve the aromatic substrate solubility in the catholyte and affect the process mechanism, determining, together with other factors, the substitution's rate and selectivity.
dc.relation.ispartofseries	Russian Journal of Electrochemistry
dc.subject	Electrochemical amination
dc.subject	Hydroxylamine
dc.subject	Radical amine
dc.subject	Radical aromatic substitution
dc.title	Electrochemical amination of benzene in aqueous solutions of sulfuric acid and an organic solvent
dc.type	Article
dc.relation.ispartofseries-issue	12
dc.relation.ispartofseries-volume	39
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	1279
dc.source.id	SCOPUS10231935-2003-39-12-SID3543036994

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