dc.contributor.author |
Vedernikov A. |
|
dc.date.accessioned |
2018-09-17T20:57:17Z |
|
dc.date.available |
2018-09-17T20:57:17Z |
|
dc.date.issued |
1997 |
|
dc.identifier.issn |
0959-9436 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/134310 |
|
dc.description.abstract |
Dibromobis(phosphine)palladium(II) complexes, PdBr2(L)2 [L = PPh3, P(p-Tol)3], react with cyclohexane and an alcoholic solution of sodium alkoxide, NaOR (R = Me, Et, Pri), at 30-60°C affording the corresponding alkyl cyclohex-1-enyl ethers, ROC6H9, in 30-140% yield on palladium both under argon and under air; benzene is inert under the reaction conditions, sodium tert-butoxide does not enter the hydrocarbon alkoxylation. |
|
dc.relation.ispartofseries |
Mendeleev Communications |
|
dc.title |
Mild alkane fimctionalisation leading to ethers: Oxidative alkoxylation of cyclohexane with the dibromobis(phosphine)palladium(II)-sodium alkoxide system |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
5 |
|
dc.relation.ispartofseries-volume |
7 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
205 |
|
dc.source.id |
SCOPUS09599436-1997-7-5-SID0042368905 |
|