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Mild alkane fimctionalisation leading to ethers: Oxidative alkoxylation of cyclohexane with the dibromobis(phosphine)palladium(II)-sodium alkoxide system

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dc.contributor.author Vedernikov A.
dc.date.accessioned 2018-09-17T20:57:17Z
dc.date.available 2018-09-17T20:57:17Z
dc.date.issued 1997
dc.identifier.issn 0959-9436
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/134310
dc.description.abstract Dibromobis(phosphine)palladium(II) complexes, PdBr2(L)2 [L = PPh3, P(p-Tol)3], react with cyclohexane and an alcoholic solution of sodium alkoxide, NaOR (R = Me, Et, Pri), at 30-60°C affording the corresponding alkyl cyclohex-1-enyl ethers, ROC6H9, in 30-140% yield on palladium both under argon and under air; benzene is inert under the reaction conditions, sodium tert-butoxide does not enter the hydrocarbon alkoxylation.
dc.relation.ispartofseries Mendeleev Communications
dc.title Mild alkane fimctionalisation leading to ethers: Oxidative alkoxylation of cyclohexane with the dibromobis(phosphine)palladium(II)-sodium alkoxide system
dc.type Article
dc.relation.ispartofseries-issue 5
dc.relation.ispartofseries-volume 7
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 205
dc.source.id SCOPUS09599436-1997-7-5-SID0042368905


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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