dc.contributor.author |
Vedernikov A. |
|
dc.contributor.author |
Sharifullin R. |
|
dc.contributor.author |
Solomonov B. |
|
dc.date.accessioned |
2018-09-17T20:57:15Z |
|
dc.date.available |
2018-09-17T20:57:15Z |
|
dc.date.issued |
1996 |
|
dc.identifier.issn |
0959-9436 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/134309 |
|
dc.description.abstract |
Alkanes RH (n-C6H14, cyclo-C6H12) and toluene react with polyhalogenomethanes CCl4, CHBr3 and CHI3 at 80-110 °C under catalysis with Wilkinson's complex, RhCl(PPh3)3, to produce halogenohydrocarbons RX and CHCl3, CH2Br2 or CH2I2 respectively with unusually high selectivity which decreases in the order: C-Hsecondry > > C-Hbenzylic > C-Hprimary. |
|
dc.relation.ispartofseries |
Mendeleev Communications |
|
dc.title |
Mild selective metathesis of alkane C-H bonds and C-X bonds of polyhalogenomethane CH4-nXn (X = Cl, n = 4; Br, I, n = 3) catalysed with chlorotris(triphenylphosphine)rhodium(I) |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
2 |
|
dc.relation.ispartofseries-volume |
6 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
54 |
|
dc.source.id |
SCOPUS09599436-1996-6-2-SID26344478874 |
|