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Mild selective metathesis of alkane C-H bonds and C-X bonds of polyhalogenomethane CH4-nXn (X = Cl, n = 4; Br, I, n = 3) catalysed with chlorotris(triphenylphosphine)rhodium(I)

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dc.contributor.author Vedernikov A.
dc.contributor.author Sharifullin R.
dc.contributor.author Solomonov B.
dc.date.accessioned 2018-09-17T20:57:15Z
dc.date.available 2018-09-17T20:57:15Z
dc.date.issued 1996
dc.identifier.issn 0959-9436
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/134309
dc.description.abstract Alkanes RH (n-C6H14, cyclo-C6H12) and toluene react with polyhalogenomethanes CCl4, CHBr3 and CHI3 at 80-110 °C under catalysis with Wilkinson's complex, RhCl(PPh3)3, to produce halogenohydrocarbons RX and CHCl3, CH2Br2 or CH2I2 respectively with unusually high selectivity which decreases in the order: C-Hsecondry > > C-Hbenzylic > C-Hprimary.
dc.relation.ispartofseries Mendeleev Communications
dc.title Mild selective metathesis of alkane C-H bonds and C-X bonds of polyhalogenomethane CH4-nXn (X = Cl, n = 4; Br, I, n = 3) catalysed with chlorotris(triphenylphosphine)rhodium(I)
dc.type Article
dc.relation.ispartofseries-issue 2
dc.relation.ispartofseries-volume 6
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 54
dc.source.id SCOPUS09599436-1996-6-2-SID26344478874


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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