dc.contributor.author |
Falin M. |
|
dc.contributor.author |
Gerasimov K. |
|
dc.contributor.author |
Latypov V. |
|
dc.contributor.author |
Leushin A. |
|
dc.date.accessioned |
2018-09-17T20:56:49Z |
|
dc.date.available |
2018-09-17T20:56:49Z |
|
dc.date.issued |
2003 |
|
dc.identifier.issn |
0953-8984 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/134297 |
|
dc.description.abstract |
SrF2 and BaF2 crystals, doped with the Yb3+ ions, have been investigated by electron paramagnetic resonance and optical spectroscopy. As-grown crystals of SrF2 and BaF2 show the two paramagnetic centres for the cubic (Tc) and trigonal (T4) symmetries of the Yb3+ ions. Empirical diagrams of the energy levels were established and the potentials of the crystal field were determined. Information was obtained on the SrF2 and BaF2 phonon spectra from the electron-vibrational structure of the optical spectra. The crystal field parameters were used to analyse the crystal lattice distortions in the vicinity of the impurity ion and the F- ion compensating for the excess positive charge in T4. Within the frames of a superposition model, it is shown that three F- ions from the nearest surrounding cube, located symmetrically with respect to the C3 axis from the side of the ion-compensator, approach the impurity ion and cling to the axis of the centre when forming T4. The F- ion located on the axis of the centre between the Yb3+ ion and ion-compensator, also approaches close to the impurity ion. |
|
dc.relation.ispartofseries |
Journal of Physics Condensed Matter |
|
dc.title |
Electron paramagnetic resonance and optical spectroscopy of Yb3+ ions in SrF2 and BaF2; an analysis of distortions of the crystal lattice near Yb3+ |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
17 |
|
dc.relation.ispartofseries-volume |
15 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
2833 |
|
dc.source.id |
SCOPUS09538984-2003-15-17-SID0038193610 |
|