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dc.contributor.author | Eremin M. | |
dc.contributor.author | Antonova I. | |
dc.date.accessioned | 2018-09-17T20:56:34Z | |
dc.date.available | 2018-09-17T20:56:34Z | |
dc.date.issued | 1998 | |
dc.identifier.issn | 0953-8984 | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/134290 | |
dc.description.abstract | The zero-field splitting of the S state due to the virtual electron transfer processes from the ligands into an unfilled shell (ln ) of a paramagnetic ion has been calculated. A simple analytical formula has been deduced for the spin-Hamiltonian parameters. The paramagnetic centres: LiCaAlF6:Fe3+, LiSrAlF6:Fe3+, Al2O3Je3+, LiCaAlF6:Gd3+, LiSrAlF6:Gd3+, Al2O3:Gd3+ and YBa2Cu3O6+y:Gd3+ with y = 0.91, 0.95 have been considered as an example. In all cases the calculated values of the D-parameter are in agreement with the electron paramagnetic resonance data within an order of magnitude and in the sign as well. | |
dc.relation.ispartofseries | Journal of Physics Condensed Matter | |
dc.title | Charge transfer process contribution to the zero-field splitting of the S-state transition ions | |
dc.type | Article | |
dc.relation.ispartofseries-issue | 25 | |
dc.relation.ispartofseries-volume | 10 | |
dc.collection | Публикации сотрудников КФУ | |
dc.relation.startpage | 5567 | |
dc.source.id | SCOPUS09538984-1998-10-25-SID0000352532 |