dc.contributor.author |
Eremin M. |
|
dc.contributor.author |
Nikitin S. |
|
dc.contributor.author |
Prosvirnin S. |
|
dc.date.accessioned |
2018-09-17T20:54:49Z |
|
dc.date.available |
2018-09-17T20:54:49Z |
|
dc.date.issued |
2002 |
|
dc.identifier.issn |
0937-9347 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/134248 |
|
dc.description.abstract |
Low-lying energy states of the [Fe3S4]0 cluster have been calculated by taking into account the double exchange, superexchange and vibronic interaction. It was found that the adiabatic potential of the excited state with S = 0 corresponds to the full delocalization of the "excess" charge. From the analysis of experimental data of Mössbauer spectroscopy and the temperature dependence of the magnetic susceptibility the double exchange parameter t ≥ 4000 cm-1 and the vibronic interaction parameter λ2/2k ≥ 2800 cm-1 have been estimated. |
|
dc.relation.ispartofseries |
Applied Magnetic Resonance |
|
dc.title |
Low-lying states of trinuclear mixed-valence cluster: [Fe3S4]0 |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
1 |
|
dc.relation.ispartofseries-volume |
23 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
97 |
|
dc.source.id |
SCOPUS09379347-2002-23-1-SID0036427066 |
|