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Conformational probes in glassy polymers: Free volume and relaxation transitions (FT-IR spectroscopy)

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dc.contributor.author Kamalova D.
dc.contributor.author Petrova S.
dc.contributor.author Remizov A.
dc.date.accessioned 2018-09-17T20:38:26Z
dc.date.available 2018-09-17T20:38:26Z
dc.date.issued 2004
dc.identifier.issn 0277-786X
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/133805
dc.description.abstract The method of conformational probes has been developed. The conformational mobility of probes introduced into poly(methyl methacrylate) (PMMA) and having different sizes of rotational fragments (Vp ≠) has been investigated. There is a correlation between the freezing temperature of probe conformational transitions (Tf) and Vp ≠. These data have been considered within the frameworks of the free volume theory and the relaxational transitions. Conformational mobility of probes in poly(vinyl trimethylsilane) (PVTMS) and poly(trimethylsilyl propyne) (PTMSP) with a large free volume fraction has been studied.
dc.relation.ispartofseries Proceedings of SPIE - The International Society for Optical Engineering
dc.subject Conformational equilibrium
dc.subject Free volume
dc.subject Infrared spectra
dc.subject Internal dynamics
dc.subject Relaxation transitions
dc.title Conformational probes in glassy polymers: Free volume and relaxation transitions (FT-IR spectroscopy)
dc.type Conference Paper
dc.relation.ispartofseries-volume 5507
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 327
dc.source.id SCOPUS0277786X-2004-5507-SID8844269189


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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