dc.contributor.author |
Vedernikov A. |
|
dc.contributor.author |
Kuramshin A. |
|
dc.contributor.author |
Solomonov B. |
|
dc.date.accessioned |
2018-09-17T20:26:28Z |
|
dc.date.available |
2018-09-17T20:26:28Z |
|
dc.date.issued |
1994 |
|
dc.identifier.issn |
0022-4936 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/133480 |
|
dc.description.abstract |
Dihalogenobis(triphenylphosphine)palladium(II) complexes 1, PdX 2(PPh3)2 (X = Cl, Br, I), reacts reversibly with saturated and aromatic hydrocarbons RH (RH = p-xylene, toluene, benzene, n-hexane, cyclohexane), slowly at ambient temperature and rapidly on heating at 70-130°C, to produce hydridodihalogeno(organo)bis(triphenylphosphine)- palladium(IV) complexes 2, Pd(H)(R)X2(PPh3)2; in the presence of bases complexes 2 eliminate hydrogen halide forming organobis(triphenylphosphine)palladium(II) halide 3, Pd(R)X(PPh 3)2. |
|
dc.relation.ispartofseries |
Journal of the Chemical Society, Chemical Communications |
|
dc.title |
Reversible thermal carbon-hydrogen bond cleavage in alkanes and arenes with dihalogenobis(triphenylphosphine)palladium(II) complexes |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
1 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
121 |
|
dc.source.id |
SCOPUS00224936-1994-1-SID0346259352 |
|