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Extremely strong OH⋯O hydrogen bonds in some 3-organophosphorus substituted pentane-2,4-diones
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| dc.contributor.author | Polozov A. | |
| dc.contributor.author | Khotinen A. | |
| dc.contributor.author | Klimovitskii E. | |
| dc.contributor.author | Kataeva O. | |
| dc.contributor.author | Litvinov I. | |
| dc.date.accessioned | 2018-09-17T20:22:54Z | |
| dc.date.available | 2018-09-17T20:22:54Z | |
| dc.date.issued | 1992 | |
| dc.identifier.issn | 0022-2860 | |
| dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/133426 | |
| dc.description.abstract | Single crystal X-ray analysis showed that 2-(2′,4′-dioxo-3′-pentyl)-trans,trans-4,6-dimethyl-2-oxo-1,3,2-dioxaphosphorinane (I) exists in the enol form, exhibiting hydrogen bonding with an R(O⋯O) of 2.397 Å. X-ray and NMR data (δ, Δδ(HD)) for 3-organophosphorus substituted pentane-2,4-diones revealed strengthening of the hydrogen bonding by the introduction of phosphorus substituents into pentane-2,4-dione, as a result of steric effects. The content of the enol form has also been determined. © 1992. | |
| dc.relation.ispartofseries | Journal of Molecular Structure | |
| dc.title | Extremely strong OH⋯O hydrogen bonds in some 3-organophosphorus substituted pentane-2,4-diones | |
| dc.type | Article | |
| dc.relation.ispartofseries-issue | C | |
| dc.relation.ispartofseries-volume | 273 | |
| dc.collection | Публикации сотрудников КФУ | |
| dc.relation.startpage | 171 | |
| dc.source.id | SCOPUS00222860-1992-273--SID0041566954 |
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Публикации сотрудников КФУ Scopus [24551]
Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.