Initiation of homolytic addition to alkenes by means of organophosphorus radical-cations

dc.contributor.author	Nikitin E.
dc.contributor.author	Zagumennov V.
dc.date.accessioned	2018-09-17T20:12:19Z
dc.date.available	2018-09-17T20:12:19Z
dc.date.issued	2000
dc.identifier.issn	0013-4686
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/133177
dc.description.abstract	An experiment is conducted which shows that the electrochemically generated radical-cations (RC) of organophosphorus compounds can react with substances possessing a weak element-hydrogen bond via a mechanism of homolytic abstraction of the hydrogen atom. A new method of electrochemical initiation of chain radical addition of thiols, dialkylthiophosphites and dialkylphosphites to alkenes is proposed which is based on these phenomena.
dc.relation.ispartofseries	Electrochimica Acta
dc.title	Initiation of homolytic addition to alkenes by means of organophosphorus radical-cations
dc.type	Article
dc.relation.ispartofseries-issue	24
dc.relation.ispartofseries-volume	45
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	3983
dc.source.id	SCOPUS00134686-2000-45-24-SID0034238627

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Публикации сотрудников КФУ Scopus [24551]
Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.