Electrochemical synthesis of diphosphonium salts, their reactivity and role in organic electrosynthesis

dc.contributor.author	Nikitin E.
dc.contributor.author	Romakhin A.
dc.contributor.author	Zagumennov V.
dc.contributor.author	Babkin Y.
dc.date.accessioned	2018-09-17T20:12:10Z
dc.date.available	2018-09-17T20:12:10Z
dc.date.issued	1997
dc.identifier.issn	0013-4686
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/133173
dc.description.abstract	Diphosphonium salts (X3P+ - +PX3) 2Y- (where X = R or R2N, Y = ClO4 or BF4) were electrochemically synthesized. The reactions between diphosphonium salts and various nucleophiles were studied. The mechanism of quasiphosphonium formation in electrochemical conditions was established by means of competitive electrochemical oxidation of tripropylphosphine in the presence of excess toluene and water. The data obtained were explained based on the supposition about the radical nature of organophosphorus radical-cations in studied reactions. © 1997 Published by Elsevier Science Ltd.
dc.relation.ispartofseries	Electrochimica Acta
dc.subject	Dodecaalkylhexaamidodiphosphonium diperchlorate
dc.subject	Electrochemical oxidation
dc.subject	Formation of quasiphosphonium
dc.subject	Hexaalkyldiphosphonium salts
dc.subject	Radical-cation
dc.title	Electrochemical synthesis of diphosphonium salts, their reactivity and role in organic electrosynthesis
dc.type	Article
dc.relation.ispartofseries-issue	13-14
dc.relation.ispartofseries-volume	42
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	2217
dc.source.id	SCOPUS00134686-1997-42-1314-SID0030704408

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