Electrochemically induced phosphorylation of alkenes

dc.contributor.author	Nikitin E.
dc.contributor.author	Zagumennov V.
dc.contributor.author	Romakhin A.
dc.contributor.author	Kosachev I.
dc.contributor.author	Babkin Y.
dc.date.accessioned	2018-09-17T20:12:07Z
dc.date.available	2018-09-17T20:12:07Z
dc.date.issued	1997
dc.identifier.issn	0013-4686
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/133172
dc.description.abstract	The processes of electrochemical phosphorylation of alkenes were investigated. It was found that anodically generated radical-cations of trialkyl phosphites, dialkyl trimethylsilyl phosphites, mono-and diamidophosphites were added to olefin molecules to give unsaturated alkenephosphonates. The anodic oxidation of tetraalkyl pyrophosphites proceeds with disintegration of initial radical-cations and leads to mixture alkane-and alkenephosphonates. Greater amounts of alkanephosphonates were formed during anodic oxidation of sodium (or lithium) dialkyl phosphites in the presence of alkenes. © 1997 Published by Elsevier Science Ltd.
dc.relation.ispartofseries	Electrochimica Acta
dc.subject	Alkene
dc.subject	Electrochemical oxidation
dc.subject	Phosphorylation
dc.subject	Radical-cation
dc.title	Electrochemically induced phosphorylation of alkenes
dc.type	Article
dc.relation.ispartofseries-issue	13-14
dc.relation.ispartofseries-volume	42
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	2205
dc.source.id	SCOPUS00134686-1997-42-1314-SID0030644908

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