dc.contributor.author |
Yuldasheva L. |
|
dc.contributor.author |
Arshinova R. |
|
dc.date.accessioned |
2018-09-14T21:00:45Z |
|
dc.date.available |
2018-09-14T21:00:45Z |
|
dc.date.issued |
1970 |
|
dc.identifier.issn |
0040-5760 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/132946 |
|
dc.description.abstract |
The calculation of the energy equilibrium according to Pitzer between the chair and boat conformations in 2,5-substituted 1,3-dioxanes is presented, as well as the energies of the electrostatic dipole interactions. It is shown that the unsymmetrical boat conformation is stabilized in 2,5-dialkyl- and in 2,2-dimethyl-5-alkyl-5-α-alkoxyalkyl-1,3-dioxanes because of the presence of hetero atoms in the ring, because of the introduction of substituents in the 2 and 5 positions, and because of the interaction between the hybridized, unshared electron pairs of the oxygen atom at the apex of the boat with the hydrogen atom of the CH2 group. © 1970 The Faraday Press, Inc. |
|
dc.relation.ispartofseries |
Theoretical and Experimental Chemistry |
|
dc.title |
Boat conformation in 2,5-substituted 1,3-dioxanes |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
5 |
|
dc.relation.ispartofseries-volume |
3 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
388 |
|
dc.source.id |
SCOPUS00405760-1970-3-5-SID34250455119 |
|