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dc.contributor.author | Yuldasheva L. | |
dc.contributor.author | Arshinova R. | |
dc.date.accessioned | 2018-09-14T21:00:45Z | |
dc.date.available | 2018-09-14T21:00:45Z | |
dc.date.issued | 1970 | |
dc.identifier.issn | 0040-5760 | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/132946 | |
dc.description.abstract | The calculation of the energy equilibrium according to Pitzer between the chair and boat conformations in 2,5-substituted 1,3-dioxanes is presented, as well as the energies of the electrostatic dipole interactions. It is shown that the unsymmetrical boat conformation is stabilized in 2,5-dialkyl- and in 2,2-dimethyl-5-alkyl-5-α-alkoxyalkyl-1,3-dioxanes because of the presence of hetero atoms in the ring, because of the introduction of substituents in the 2 and 5 positions, and because of the interaction between the hybridized, unshared electron pairs of the oxygen atom at the apex of the boat with the hydrogen atom of the CH2 group. © 1970 The Faraday Press, Inc. | |
dc.relation.ispartofseries | Theoretical and Experimental Chemistry | |
dc.title | Boat conformation in 2,5-substituted 1,3-dioxanes | |
dc.type | Article | |
dc.relation.ispartofseries-issue | 5 | |
dc.relation.ispartofseries-volume | 3 | |
dc.collection | Публикации сотрудников КФУ | |
dc.relation.startpage | 388 | |
dc.source.id | SCOPUS00405760-1970-3-5-SID34250455119 |