The stability of metal complexes with 8-mercaptoquinoline and alkyl-substituted 8-mercaptoquinolines in dimethylformamide

dc.contributor.author	Ulakhovich N.
dc.contributor.author	Budnikov H.
dc.contributor.author	Gorbunova T.
dc.contributor.author	Sturis A.
dc.date.accessioned	2018-09-14T21:00:11Z
dc.date.available	2018-09-14T21:00:11Z
dc.date.issued	1984
dc.identifier.issn	0039-9140
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/132938
dc.description.abstract	The stoichiometry and stability constants of 8-mercaptoquinoline and alkyl-8-mercaptoquinoline complexes of Zn(II), Cd(II), Pb(II), Ni(II), Bi(III) and Ag(I) were determined potentiometrically in dimethylformamide. The stability of the 8-mercaptoquinolinates decreases in the order Ag(I) ≫ Bi(III) ≫ Ni(II) ≫ Pb(II) ≫ Cd(II) ≫ Zn(II). Metal 7-methyl-8-mercaptoquinolinates are the most stable. The presence of the alkyl group in the 2-position (which has a steric effect) lowers the strength of metal-ligand bonding. © 1984.
dc.relation.ispartofseries	Talanta
dc.title	The stability of metal complexes with 8-mercaptoquinoline and alkyl-substituted 8-mercaptoquinolines in dimethylformamide
dc.type	Article
dc.relation.ispartofseries-issue	9
dc.relation.ispartofseries-volume	31
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	727
dc.source.id	SCOPUS00399140-1984-31-9-SID48549108421

Files in this item

Size: 43.68Kb

Format: PDF

Публикации сотрудников КФУ Scopus [24551]
Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.