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On the influence of covalence on paramagnetic spin-lattice relaxation

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dc.contributor.author Klimachev A.
dc.date.accessioned 2018-09-14T20:55:06Z
dc.date.available 2018-09-14T20:55:06Z
dc.date.issued 1973
dc.identifier.issn 0038-5697
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/132851
dc.description.abstract The paramagnetic spin-lattice relaxation times of an isolated Ir4+ ion inserted in the crystalline lattice (NH4)2PtCl6 are computed. The computation is carried out for a Van Vleck relaxation mechanism taking account of the possibility of the formation of molecular orbits. It is shown that the effect of covalence in this case can be taken into account effectively in terms of the modified quantities -r2 and -r4, the mean square and mean fourth power of the electron radius. The results of calculations agree better with experiment as compared to estimates obtained without using molecular orbitals. © 1973 Consultants Bureau.
dc.relation.ispartofseries Soviet Physics Journal
dc.title On the influence of covalence on paramagnetic spin-lattice relaxation
dc.type Article
dc.relation.ispartofseries-issue 7
dc.relation.ispartofseries-volume 14
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 910
dc.source.id SCOPUS00385697-1973-14-7-SID34250442954


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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