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Temperature dependence of the rate constants of heterogeneous electron-transfer reactions

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dc.contributor.author Kargin Y.
dc.contributor.author Vorontsova L.
dc.contributor.author Manapova L.
dc.contributor.author Kuzovenko S.
dc.contributor.author Gainutdinova G.
dc.date.accessioned 2018-09-14T20:54:17Z
dc.date.available 2018-09-14T20:54:17Z
dc.date.issued 1989
dc.identifier.issn 0038-5387
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/132838
dc.description.abstract The aim of this work was to use faradaic impedance in studying solvent effects on the preexponential factor of the rate constants ks of one-electron reduction of a number of organic compounds at mercury. The standard free energies of activation of the reactions studied correlate with the dielectric properties of the solvents, and decrease in the order of acetonitrile-acetone-dimethylformamide-benzonitrile. Secondly the solvent influences not only the free energy of activation but also the value of the preexponential factor.
dc.relation.ispartofseries Soviet electrochemistry
dc.title Temperature dependence of the rate constants of heterogeneous electron-transfer reactions
dc.type Article
dc.relation.ispartofseries-issue 8
dc.relation.ispartofseries-volume 24
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 1030
dc.source.id SCOPUS00385387-1989-24-8-SID0024612804


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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