Temperature dependence of the rate constants of heterogeneous electron-transfer reactions

dc.contributor.author	Kargin Y.
dc.contributor.author	Vorontsova L.
dc.contributor.author	Manapova L.
dc.contributor.author	Kuzovenko S.
dc.contributor.author	Gainutdinova G.
dc.date.accessioned	2018-09-14T20:54:17Z
dc.date.available	2018-09-14T20:54:17Z
dc.date.issued	1989
dc.identifier.issn	0038-5387
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/132838
dc.description.abstract	The aim of this work was to use faradaic impedance in studying solvent effects on the preexponential factor of the rate constants ks of one-electron reduction of a number of organic compounds at mercury. The standard free energies of activation of the reactions studied correlate with the dielectric properties of the solvents, and decrease in the order of acetonitrile-acetone-dimethylformamide-benzonitrile. Secondly the solvent influences not only the free energy of activation but also the value of the preexponential factor.
dc.relation.ispartofseries	Soviet electrochemistry
dc.title	Temperature dependence of the rate constants of heterogeneous electron-transfer reactions
dc.type	Article
dc.relation.ispartofseries-issue	8
dc.relation.ispartofseries-volume	24
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	1030
dc.source.id	SCOPUS00385387-1989-24-8-SID0024612804

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Публикации сотрудников КФУ Scopus [24551]
Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.