The spectra and structure of sulphur-containing organic compounds-IV. The vibrational spectra and conformations of haloidmethylmethylsulphones CH3SO2CH2X

dc.contributor.author	Remizov A.
dc.contributor.author	Bilalov F.
dc.contributor.author	Pominov I.
dc.date.accessioned	2018-09-14T20:47:09Z
dc.date.available	2018-09-14T20:47:09Z
dc.date.issued	1987
dc.identifier.issn	0584-8539
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/132719
dc.description.abstract	The i.r. and Raman spectra of the haloidmethylmethylsulphones CH3SO2CH2Cl (I) and CH3SO2CH2Br (II) in their liquid, solution and crystalline states have been recorded. The presence of a mixture of trans and gauche conformations has been established. The temperature dependence of the i.r. spectra has been investigated and the value ΔH = H(gauche) - H(trans) found. The band dichroism of the polarized i.r. spectra of crystalline I and II has been considered. The frequencies of the torsion vibrations have been found and the value of the internal rotation barrier measured. The interpretation of vibrational spectra is given and a normal coordinate analysis has been carried out. © 1987.
dc.relation.ispartofseries	Spectrochimica Acta Part A: Molecular Spectroscopy
dc.title	The spectra and structure of sulphur-containing organic compounds-IV. The vibrational spectra and conformations of haloidmethylmethylsulphones CH3SO2CH2X
dc.type	Article
dc.relation.ispartofseries-issue	3
dc.relation.ispartofseries-volume	43
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	309
dc.source.id	SCOPUS05848539-1987-43-3-SID45949125783

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