Composition, properties, and structure of palladium(II) chlorides in aqueous solution

dc.contributor.author	Vul'fson S.
dc.contributor.author	Glebov A.
dc.contributor.author	Nagaitseva I.
dc.contributor.author	Tarasov O.
dc.contributor.author	Sal'nikov Y.
dc.contributor.author	Vereshchagin A.
dc.date.accessioned	2018-09-14T20:46:17Z
dc.date.available	2018-09-14T20:46:17Z
dc.date.issued	1990
dc.identifier.issn	0568-5230
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/132699
dc.description.abstract	The composition, stability, and structure of palladium(II) chloride complexes in hydrochloric acid media have been determined using nuclear-magnetic relaxation, magnetochemical methods, and Rayleigh light scattering. The predominant form in solution for palladium(II) concentrations greater than 0.005 moles/liter is the octahedral Pd6Cl12 or Pd6Cl14 2-, which has antiferromagnetic properties in contrast with the paramagnetic properties of the mononuclear aquachloride. The polarizability anisotropy of Pd-Cl bonds with terminal and bridging chlorine atoms has been determined. © 1991 Plenum Publishing Corporation.
dc.relation.ispartofseries	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
dc.title	Composition, properties, and structure of palladium(II) chlorides in aqueous solution
dc.type	Article
dc.relation.ispartofseries-issue	11
dc.relation.ispartofseries-volume	39
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	2237
dc.source.id	SCOPUS05685230-1990-39-11-SID34249922939

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