dc.contributor.author |
Vul'fson S. |
|
dc.contributor.author |
Glebov A. |
|
dc.contributor.author |
Nagaitseva I. |
|
dc.contributor.author |
Tarasov O. |
|
dc.contributor.author |
Sal'nikov Y. |
|
dc.contributor.author |
Vereshchagin A. |
|
dc.date.accessioned |
2018-09-14T20:46:17Z |
|
dc.date.available |
2018-09-14T20:46:17Z |
|
dc.date.issued |
1990 |
|
dc.identifier.issn |
0568-5230 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/132699 |
|
dc.description.abstract |
The composition, stability, and structure of palladium(II) chloride complexes in hydrochloric acid media have been determined using nuclear-magnetic relaxation, magnetochemical methods, and Rayleigh light scattering. The predominant form in solution for palladium(II) concentrations greater than 0.005 moles/liter is the octahedral Pd6Cl12 or Pd6Cl14 2-, which has antiferromagnetic properties in contrast with the paramagnetic properties of the mononuclear aquachloride. The polarizability anisotropy of Pd-Cl bonds with terminal and bridging chlorine atoms has been determined. © 1991 Plenum Publishing Corporation. |
|
dc.relation.ispartofseries |
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science |
|
dc.title |
Composition, properties, and structure of palladium(II) chlorides in aqueous solution |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
11 |
|
dc.relation.ispartofseries-volume |
39 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
2237 |
|
dc.source.id |
SCOPUS05685230-1990-39-11-SID34249922939 |
|