Production of some derivatives of 1,3,2-dioxastibinane and their vibrational spectra

Abstract

1. 2-Chloro-, 2-methoxy-, and 2-tert-butoxy-4,6,6-trimethyl-1,3,2-dioxastibinanes and 2-tert-butoxy-5,5-dimethyl-and 2-tert-butoxy-4-methyl-1,3,2-dioxastibinanes were synthesized by the transetherification of chlorodiethoxy-, trimethoxy-, and tri-tert-butoxyantimony with the respective glycols. 2. According to the data on the vibration spectra, the 2-chloro and 2-alkoxy derivatives of 1,3,2-dioxastibinane are associated at the Sb-O bonds in the crystalline phase. The degree of association is determined by steric factors. 2-tert-Butoxy-4,6,6-trimethyl-1,3,2-dioxastibinane exists in the monomeric form. © 1985 Plenum Publishing Corporation.