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Contribution of intermolecular associates and inversion of pyramid of antimony bonds in conformational exchange of certain 1,3,2-dioxastibinanes and 1,3,2-dioxastibepines

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dc.contributor.author Arbuzov B.
dc.contributor.author Aganov A.
dc.contributor.author Klochkov V.
dc.contributor.author Samitov Y.
dc.contributor.author Mareev Y.
dc.contributor.author Vinogradova V.
dc.date.accessioned 2018-09-14T20:44:06Z
dc.date.available 2018-09-14T20:44:06Z
dc.date.issued 1984
dc.identifier.issn 0568-5230
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/132648
dc.description.abstract 1. It has been shown for the first time by means of1H NMR that in solutions of cyclic compounds of trivalent antimony, dimeric structures with the participation, of endocyclic and exocyclic O atoms are realized. The molecular dynamics are determined by conformational conversions and also by the process of rupture and formation of dimeric bridge bonds Sb...O, this process of bond rupture and formation being the limiting stage of the overall process. The process mechanism has been established, and the energetics have been estimated. 2. The dominant conformations in the monomeric form have been determined, and the characteristics of the1H and13C NMR spectra are given for the particular compounds that have been studied. © 1985 Plenum Publishing Corporation.
dc.relation.ispartofseries Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
dc.title Contribution of intermolecular associates and inversion of pyramid of antimony bonds in conformational exchange of certain 1,3,2-dioxastibinanes and 1,3,2-dioxastibepines
dc.type Article
dc.relation.ispartofseries-issue 7
dc.relation.ispartofseries-volume 33
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 1380
dc.source.id SCOPUS05685230-1984-33-7-SID34250132518


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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