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dc.contributor.author | Shagidullin R. | |
dc.contributor.author | Shakirov I. | |
dc.contributor.author | Plyamovatyi A. | |
dc.contributor.author | Arshinova R. | |
dc.contributor.author | Nuretdinov I. | |
dc.date.accessioned | 2018-09-14T20:42:57Z | |
dc.date.available | 2018-09-14T20:42:57Z | |
dc.date.issued | 1984 | |
dc.identifier.issn | 0568-5230 | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/132644 | |
dc.description.abstract | 1. Unsubstituted 2-dialkylamino-1,3,2-dioxaphosphorinanes with three- and four-coordinated phosphorus exist as a mixture of two conformers in the liquid and solutions of polar solvents according to the vibration spectral data and calculations by the method of atomic-atomic potential functions; the conformers with an equatorial orientation of the dialkylamino group is energetically more advantageous and is realized in a crystal. 2. The cis-isomer of 2-diethylamino-2-thio-4-methyl-1,3,2-dioxaphosphorinane is conformationally homogeneous. Conformational equilibrium in which three conformers participate based on the results of the calculations: two chair and boat forms, is found for the less stable trans-isomer. © 1985 Plenum Publishing Corporation. | |
dc.relation.ispartofseries | Bulletin of the Academy of Sciences of the USSR Division of Chemical Science | |
dc.title | Vibration spectra and conformations of 1,3,2-dioxaphosphorinanes containing an exocyclic P-N bond | |
dc.type | Article | |
dc.relation.ispartofseries-issue | 11 | |
dc.relation.ispartofseries-volume | 33 | |
dc.collection | Публикации сотрудников КФУ | |
dc.relation.startpage | 2306 | |
dc.source.id | SCOPUS05685230-1984-33-11-SID34250141181 |