dc.contributor.author |
Shagidullin R. |
|
dc.contributor.author |
Shakirov I. |
|
dc.contributor.author |
Plyamovatyi A. |
|
dc.contributor.author |
Arshinova R. |
|
dc.contributor.author |
Nuretdinov I. |
|
dc.date.accessioned |
2018-09-14T20:42:57Z |
|
dc.date.available |
2018-09-14T20:42:57Z |
|
dc.date.issued |
1984 |
|
dc.identifier.issn |
0568-5230 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/132644 |
|
dc.description.abstract |
1. Unsubstituted 2-dialkylamino-1,3,2-dioxaphosphorinanes with three- and four-coordinated phosphorus exist as a mixture of two conformers in the liquid and solutions of polar solvents according to the vibration spectral data and calculations by the method of atomic-atomic potential functions; the conformers with an equatorial orientation of the dialkylamino group is energetically more advantageous and is realized in a crystal. 2. The cis-isomer of 2-diethylamino-2-thio-4-methyl-1,3,2-dioxaphosphorinane is conformationally homogeneous. Conformational equilibrium in which three conformers participate based on the results of the calculations: two chair and boat forms, is found for the less stable trans-isomer. © 1985 Plenum Publishing Corporation. |
|
dc.relation.ispartofseries |
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science |
|
dc.title |
Vibration spectra and conformations of 1,3,2-dioxaphosphorinanes containing an exocyclic P-N bond |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
11 |
|
dc.relation.ispartofseries-volume |
33 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
2306 |
|
dc.source.id |
SCOPUS05685230-1984-33-11-SID34250141181 |
|