Показать сокращенную информацию
dc.contributor.author | Arbuzov B. | |
dc.contributor.author | Dianova E. | |
dc.contributor.author | Samitov Y. | |
dc.date.accessioned | 2018-09-14T20:41:23Z | |
dc.date.available | 2018-09-14T20:41:23Z | |
dc.date.issued | 1982 | |
dc.identifier.issn | 0568-5230 | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/132614 | |
dc.description.abstract | 1. The reaction of 2-R-5-methyl-1,2,3-diazaphospholeswith diphenyldtazomethane leads to the formation of 2-R-4-methyl-6,6-diphenyl-1-phospha-2,3-diazabicyclo[3.1.0]hex-3-enes which, upon heating with alcohols and reaction with dry HCl, convert to derivatives of 2,3,4,5-tetrahydro-1,2-diaza-3-phosphorines. 2. The stereochemical dependence of the3JP(III)CCH vicinal coupling constant on the dihedral angle for these phosphorines indicated predominant half-chair conformation with pseudoequatorial orientation of the phosphorus unshared electron pair orbital. © 1983 Plenum Publishing Corporation. | |
dc.relation.ispartofseries | Bulletin of the Academy of Sciences of the USSR Division of Chemical Science | |
dc.title | 1H and31P NMR study of the structure of 2-R-4-methyl-6,6-diphenyl-1-phospha-2,3-diazabicyclo [3.1.0]hex-3-ene and 2,3,4,5-tetrahydro-1,2,3-diazaphosphorine derivatives | |
dc.type | Article | |
dc.relation.ispartofseries-issue | 12 | |
dc.relation.ispartofseries-volume | 31 | |
dc.collection | Публикации сотрудников КФУ | |
dc.relation.startpage | 2414 | |
dc.source.id | SCOPUS05685230-1982-31-12-SID34250234459 |