Stereochemistry of organophosphorus compounds 15. Synthesis and permutational lability of 1,6,10-trioxa-8,8-dimethyl[(5-methoxy)-5-phosphaspiro(4.5)]dec-2-ene

dc.contributor.author	Arbuzov B.
dc.contributor.author	Samitov Y.
dc.contributor.author	Mareev Y.
dc.contributor.author	Vinogradova V.
dc.date.accessioned	2018-09-14T20:33:47Z
dc.date.available	2018-09-14T20:33:47Z
dc.date.issued	1977
dc.identifier.issn	0568-5230
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/132577
dc.description.abstract	1. We have synthesized 1,6,10-trioxa-8,8-dimethyl[(5-methoxy)-5-phosphaspiro(4.5)]dec-2-ene, a compound in which the trigonal-bipyramidal phosphorus bond arrangment undergoes pseudorotation at temperatures below 36°C. Thermodynamic activation parameters for the pseudorotation process have been evaluated from the observed temperature variation of the parameters of the1H NMR spectrum. 2. The enol acetate of β-neopentylglycolphosphonepropionic aldehyde has been prepared. © 1978 Plenum Publishing Corporation.
dc.relation.ispartofseries	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
dc.title	Stereochemistry of organophosphorus compounds 15. Synthesis and permutational lability of 1,6,10-trioxa-8,8-dimethyl[(5-methoxy)-5-phosphaspiro(4.5)]dec-2-ene
dc.type	Article
dc.relation.ispartofseries-issue	9
dc.relation.ispartofseries-volume	26
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	1852
dc.source.id	SCOPUS05685230-1977-26-9-SID34250293958

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Публикации сотрудников КФУ Scopus [24551]
Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.