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Ionization constants and reactivity of spirophosphoranes with a P-H bond when reacted with diphenyldiazomethane

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dc.contributor.author Ovchinnikov V.
dc.contributor.author Pudovik M.
dc.contributor.author Galkin V.
dc.contributor.author Cherkasov R.
dc.contributor.author Pudovik A.
dc.date.accessioned 2018-09-14T20:32:52Z
dc.date.available 2018-09-14T20:32:52Z
dc.date.issued 1977
dc.identifier.issn 0568-5230
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/132563
dc.description.abstract 1. The potentiometric titration method was used to determine the ionization constants of some spiro- and monocyclophosphoranes, which contain the P-H bond, in absolute n-propanol. 2. A study of the reaction rate of these phosphoranes with diphenyldiazomethane disclosed that their reactivity increases with increase in the acidity. In this connection the proton of the P-H fragment is more labile in the spirocyclic than in the monocyclic phosphoranes. © 1977 Plenum Publishing Corporation.
dc.relation.ispartofseries Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
dc.title Ionization constants and reactivity of spirophosphoranes with a P-H bond when reacted with diphenyldiazomethane
dc.type Article
dc.relation.ispartofseries-issue 2
dc.relation.ispartofseries-volume 26
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 393
dc.source.id SCOPUS05685230-1977-26-2-SID34250294907


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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