dc.contributor.author |
Raevskii O. |
|
dc.contributor.author |
Khalitov F. |
|
dc.contributor.author |
Mumzhieva N. |
|
dc.contributor.author |
Gilyazov M. |
|
dc.contributor.author |
Zakirov D. |
|
dc.contributor.author |
Safin I. |
|
dc.contributor.author |
Aganov A. |
|
dc.date.accessioned |
2018-09-14T20:31:45Z |
|
dc.date.available |
2018-09-14T20:31:45Z |
|
dc.date.issued |
1976 |
|
dc.identifier.issn |
0568-5230 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/132543 |
|
dc.description.abstract |
1. In the liquid state, in solution, and in one of its crystalline modifications, the chlorohydrate of dichloromethylphosphonic acid exists as a mixture of two nonrotating isomers of Cs and C1 symmetries (gauche-gauche and gauche-trans orientation of the two CHCl2 group chlorines with respect to the P=O bond). The conformers are individually stabilized in the other crystalline modifications. 2. It is assumed that weak intramolecular bonds of the C-H...O=P type play a role in the stabilizing the conformer with the chlorine in the gauche-trans orientation. © 1977 Plenum Publishing Corporation. |
|
dc.relation.ispartofseries |
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science |
|
dc.title |
Study of the spatial structure of the chloroanhydride of dichloromethylphosphonic acid by a combination of various physical methods |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
12 |
|
dc.relation.ispartofseries-volume |
25 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
2514 |
|
dc.source.id |
SCOPUS05685230-1976-25-12-SID34250289093 |
|